Al Nasri, N, Patra, N, Jayaseelan, D.D. and Lee, W.E. (2017) Water vapour corrosion of rare earth monosilicates for environmental barrier coatings application. Ceramics International, 43(10), pp. 7393-7400. ISSN (print) 0272-8842
Abstract
Water vapour corrosion resistance of five rare earth monosilicates Y2SiO5, Gd2SiO5, Er2SiO5, Yb2SiO5, and Lu2SiO5 was investigated during testing at 1350 ˚C for up to 166 h in static air with 90% water vapour. Four of the RE-silicates showed little weight gain (0.859 mg cm-2) after 166 h of exposure. Prior to testing the microstrucre consists of equiaxed grains of 4- 7 ± 0.4 µm. XRD analysis showed that after 50 h exposure to water vapour corrosion Y, Er, Yb and Lu-silicates had both mono and disilicates present on their surfaces as a result of the reaction between monosilicate and water vapour to form disilicate, while Gd-silicate has converted completely to G4.67Si3O13 making it less stable for environmental barrier coatings application. The microstructures of corroded Y, Er, Yb and Lu-silicates contain ridges and cracks, while that of Gd-silicate contains rounded grains suggesting melting along with striped contract grains.
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