Some organic-inorganic nanocomposites and their optoelectronic properties

Diaz Mesa, Ivonne Marcela, Foot, Peter and Kresinski, Roman (2011) Some organic-inorganic nanocomposites and their optoelectronic properties. In: Hybrid Materials 2011 : Second International Conference on Multifunctional, Hybrid and Nanomaterials; 06 - 10 Mar 2011, Strasbourg, France. (Unpublished)

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Abstract

Intercalation of organic guest into the interlayer space of inorganic host materials such as clays is an effective way of producing well-organised nanocomposites with properties that can be used for various industrial applications, including the production of electronic devices. Single crystals of lamellar-structured thiophosphates, particularly MnPS3 and Pd3P2S8, have been prepared from the pure elements via chemical vapour transport. The hybrid compounds were characterised by powder x-ray diffractometry and by infrared and Raman spectroscopy. Intercalation of cationic species into these compounds was achieved under mild conditions, producing significant increases in the interlayer spacing. The optoelectronic properties of the host compounds were enhanced by the presence of organic intercalants, and the photoluminescence of intercalated species such as poly(phenylene vinylene) [PPV] was significantly more stable than that of the free polymer.

Item Type: Conference or Workshop Item (Poster)
Event Title: Hybrid Materials 2011 : Second International Conference on Multifunctional, Hybrid and Nanomaterials
Uncontrolled Keywords: Nanocomposites; organic-inorganic; luminescence
Research Area: Chemistry
Metallurgy and materials
Faculty, School or Research Centre: Faculty of Science, Engineering and Computing (until 2017) > Materials Research Centre
Depositing User: Peter Foot
Date Deposited: 19 Oct 2018 07:46
Last Modified: 19 Oct 2018 07:46
URI: http://eprints.kingston.ac.uk/id/eprint/39700

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